Search results

1 – 7 of 7
Article
Publication date: 4 September 2017

Mozhgan Hosseinnezhad and Kamaladin Gharanjig

The purpose of this paper is to study assembling parameters in dye-sensitised solar cells (DSSCs) performance. For this end, 3a,7a-dihydroxy-5ß-cholanic acid (cheno) are selected…

Abstract

Purpose

The purpose of this paper is to study assembling parameters in dye-sensitised solar cells (DSSCs) performance. For this end, 3a,7a-dihydroxy-5ß-cholanic acid (cheno) are selected as anti-aggregation agent and two solutions, namely, tetrabutyl ammonium iodide and (PMII)IL used as electrolyte.

Design/methodology/approach

A series of organic dyes were selected using N-substituents carbazole as electron donor group and acrylic acid and cyanoacrylic acid as electron acceptor groups. Absorption properties of purified dyes were studied in solution and on photoelectrode substrate. DSSCs were prepared in the presence of anti-aggregation agent and different electrolyte to determine the photovoltaic performance of each dyes.

Findings

The results showed that all organic dyes form J-aggregation on the photoanode substrate in the absence of anti-aggregation agent and the amounts of aggregation were reduced in the presence of anti-aggregation agent. DSSCs were fabricated in the presence of anti-aggregation agent. The photovoltaic properties were improved using tetrabutyl ammonium iodide as electrolyte. The maximum power conversion efficiency was achieved for D12 in the presence of cheno and tetrabutyl ammonium iodide as anti-aggregation agent and electrolyte, respectively.

Social implications

Organic dye attracts more and more attention due to low cost, facile route synthesis and less hazardous.

Originality/value

The effect of anti-aggregation agent and electrolyte on DSSCs performance was investigated for the first time.

Details

Pigment & Resin Technology, vol. 46 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 28 March 2024

Mozhgan Hosseinnezhad, Kamaladin Gharanjig, Shahid Adeel and Alireza Mahmoudi Nahavandi

Agricultural waste and food sources are some of the pollutants of the environment. One of these wastes is the peel of fruits that cannot be consumed as food. In this regard…

Abstract

Purpose

Agricultural waste and food sources are some of the pollutants of the environment. One of these wastes is the peel of fruits that cannot be consumed as food. In this regard, walnut husk (WH) and oleaster peel (PO) are known as two important sources of tannin and are bulky wastes. Because of the high percentage of tannin, these materials can be used as a natural source for the preparation of bio-mordant in the dyeing process.

Design/methodology/approach

In this study, Reseda and Madder were used as natural dyes in the presence of a mixture of two bio-mordants. WH and PO were selected as bio-mordant. All natural resources are extracted to obtain the juice. The phenolic percentage of tannin-containing extracts was evaluated and then it was used for wool yarns by premordanting method. The results of evaluating the fastness properties using the ISO method.

Findings

The most important achievement of this research is the use of agricultural waste in the dyeing process to reduce environmental pollution and create added value. All compounds rich in tannin have some phenolic components, therefore the amount of phenolic content of these extracts was evaluated. The effect of mixing the mordant on the color characteristics of the yarns was investigated and the results showed that changing the ratio of the combination of two mordant is effective on the K/S values. The results of evaluating the fastness properties using the ISO method showed that the washing, rubbing and light fastness in the presence of mordant is good, good and moderate, respectively.

Originality/value

In this paper, to the best of the authors’ knowledge, for the first time, the combination of two natural extracts obtained from agricultural waste has been used to create a new bio-mordant on fibers and improve stability.

Details

Research Journal of Textile and Apparel, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1560-6074

Keywords

Article
Publication date: 2 September 2019

Mozhgan Hosseinnezhad and Hanieh Shaki

The purpose of this paper is to study the substituent effect in dye-sensitized solar cells’ (DSSCs) performance. For this end, three new metal organic dyes with DPA structure were…

Abstract

Purpose

The purpose of this paper is to study the substituent effect in dye-sensitized solar cells’ (DSSCs) performance. For this end, three new metal organic dyes with DPA structure were synthesized. For investigation of the substituent effect, two different anchoring groups, namely, 1,3-dioxo-1Hbenz[de]isoquinolin-2(3H)-yl)benzenesulfonamides and 1,8-naphthalimide, were used.

Design/methodology/approach

Three organic dyes based on azo were selected, which contain various electron donor groups. Absorption properties of purified dyes were studied in solution and on photoelectrode (TiO2 and ZnO) substrate. DSSCs were prepared to determine the photovoltaic performance of each photosensitizer.

Findings

The results showed that all organic dyes form J-aggregation on the photoanode substrate. Cyclic voltammetry results for all organic dyes ensured an energetically permissible and thermodynamically favorable charge transfer throughout the continuous cycle of photo-electric conversion. The results illustrate conversion efficiencies of cells based on solution Dyes 1, 2 and 3 and TiO2 as 3.44, 4.71 and 4.82 per cent, respectively. The conversion efficiencies of cells based on solution Dye 1, 2 and 3 and ZnO are 3.21, 4.09 and 4.14 per cent, respectively.

Practical implications

In this study, the development of effect of assembling materials, offering improved photovoltaic properties.

Social implications

Organic dye attracts more and more attention because of its low-cost, facile route synthesis and less-hazardous properties.

Originality/value

To the best of the authors’ knowledge, the effect of anchoring agent and nanostructure on DSSCs performance was investigated for the first time.

Details

Pigment & Resin Technology, vol. 48 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 5 April 2023

Mozhgan Hosseinnezhad and Zahra Ranjbar

The purpose of this paper is to introduce flexible dye-sensitized solar cells (FDSSCs).

Abstract

Purpose

The purpose of this paper is to introduce flexible dye-sensitized solar cells (FDSSCs).

Design/methodology/approach

In the third generation solar cells, glass was used as a substrate, which due to its high weight and fragility, was not possible to produce continuously. However, in flexible solar cells, flexible substrates are used as new technology. The most important thing may choose a suitable substrate to produce a photovoltaic (PV) device with optimal efficiency.

Findings

Conductive plastics or metallic foils are the two main candidates for glass replacement, each with its advantages and disadvantages. As some high-temperature methods are used to prepare solar cells, metal substrates can be used to prepare PV devices without any problems. In contrast to the advantage of high thermal resistance in metals, metal substrates are dark and do not transmit enough light. In other words, metal substrates have a high loss of photon energy. Like all technologies, PV devices with polymer substrates have technical disadvantages.

Practical implications

In this study, the development of FDSSCs offers improved photovoltaic properties.

Social implications

The most important challenge is the poor thermal stability of polymers compared to glass and metal, which requires special methods to prepare polymer solar cells. The second important point is choosing the suitable components and materials for this purpose.

Originality/value

Dependence of efficiency and performance of the device on the angle of sunlight, high-cost preparation devices components, limitations of functional materials such as organic-mineral sensitizers, lack of close connection between practical achievements and theoretical results and complicated fabrication process and high weight.

Details

Pigment & Resin Technology, vol. 52 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 4 July 2016

Mozhgan Hosseinnezhad

Dye-sensitised solar cells (DSSCs) have attracted a great deal of interest. Dye molecules are key materials in DSSCs that produce electrons. This study reports on synthesis of the…

Abstract

Purpose

Dye-sensitised solar cells (DSSCs) have attracted a great deal of interest. Dye molecules are key materials in DSSCs that produce electrons. This study reports on synthesis of the organic dyes and investigation their performance in DSSCs.

Design/methodology/approach

A series of new organic dyes were prepared using double rhodanine as the fundamental electron-acceptor group and aldehydes with varying substituents as the electron-donor groups. These dyes were first purified and then characterised by analytical techniques. DSSCs were fabricated to determine the photovoltaic behaviour and conversion efficiency of each individual dye.

Findings

Results demonstrated that all the dyes form j-type aggregates on the nano TiO2. All dyes in DSSC structure show suitable power conversion efficiency, and Dye 5 due to presence of OCH3 and OiPr presents maximum conversion efficiency.

Practical implications

In the search for high-efficiency organic dyes for DSSCs, development of new materials offering optimised photochemical stabilities as well as suitable optical and electrical properties is importance.

Social implications

Organic dyes as photosensitisers are interesting due to low cost, relatively facile dye synthesis and capability of easy molecular tailoring.

Originality/value

A series of new organic metal-free dyes were prepared as sensitisers for DSSCs for the first time.

Abstract

Details

Pigment & Resin Technology, vol. 52 no. 3
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 7 September 2015

Kamaladin Gharanjig and Mozhgan Hosseinnezhad

The purpose of this paper is to prepare new organic dyes and use them as sensitisers in dye-sensitised solar cells. These dyes were synthesised and purified and then characterised…

Abstract

Purpose

The purpose of this paper is to prepare new organic dyes and use them as sensitisers in dye-sensitised solar cells. These dyes were synthesised and purified and then characterised by analytical techniques. Spectrophotometric evaluations of the prepared dyes were carried out in solution and on a nano-anatase TiO2 substrate to assess the possible changes in the status of the dyes in different environments. Finally, the photovoltaic properties were investigated in dye-sensitised solar cells.

Design/methodology/approach

So as to synthesise dyes, N-substituents carbazole were utilised as the fundamental electron donor group and cyanoacrylic acid or acrylic acid as electron acceptor anchoring groups. Purified dyes were dissolved in solution and coated on TiO2 substrate. Finally, dye-sensitised solar cells were fabricated to determine the photovoltaic behaviour and conversion efficiency of each individual dye.

Findings

The results showed that the dyes form j-type aggregates on the nano TiO2. The oxidation potential of synthesised carbazole dyes is > 0.2 V vs Fc/Fc+; hence, their high performance in dye-sensitised solar cells. Dye 3 exhibited 2.11 per cent of conversion efficiency in comparison to 2.89 per cent for the identical cells with Dye 9 containing cyanoacrylic acid which acted as the best acceptor group.

Practical implications

The novel dyes look as promising as highly light fast, efficient dyes for dye-sensitised solar cells.

Social implications

Organic dye provides low cost and less hazardous materials for dye-sensitised solar cells.

Originality/value

A series of new organic dyes were synthesised as sensitisers for dye-sensitised solar cells for the first time.

1 – 7 of 7