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This study aims to prepare a low-formaldehyde and environmentally friendly glucose-lignin-based phenolic resin.

The authors directly used lignin to substitute formaldehyde to prepare lignin-based phenolic resin (LPF) with urea as formaldehyde absorbent. To improve the performance of the adhesive, the biobased glucose was introduced and the modified glucose-LPF (GLPF) was obtained.

The results showed that when the replacing amount of lignin to formaldehyde reached 15 Wt.%, the physical properties of the prepared LPF met the Chinese national standard, and the bonding strength increased by 21.9%, from 0.75 to 0.96 MPa, compared with PF. The addition of glucose boost the performance of wood adhesive, for example, the free phenol content of the obtained GLPF was significantly reduced by 79.11%, from 5.60% to 1.17%, the bonding strength (1.19 MPa) of GLPF increased by 19.3% in comparison to LPF and the curing temperature of GLPF decreased by 13.08%.

The low-formaldehyde and environmentally friendly GLPF has higher bonding strength and lower curing temperature, which is profitable to industrial application.

The prepared GLPF has lower free formaldehyde and formaldehyde emission, which is cost-effective and beneficial to human health.

The joint work of lignin and glucose provides the wood adhesive with increased bonding strength, decreased free phenol content and reduced curing temperature.

Polyurethane concrete has a high strength-to-weight ratio in the short term, and the strength-to-weight ratio stage during the maintenance period is critical. Freeze-thaw cycles have a noticeable damaging effect on the durability of polyurethane concrete. The engineering specification of polyurethane concrete with incomplete hydration reaction must be studied, as well as the development of internal structure during curing. In this paper, the polyurethane concrete tests were set up under eight distinct maintenance settings based on the climate features of the northern area and the service environment. The test results were evaluated to determine the effect of the number of early freeze-thaw cycles and the time node of early freeze-thaw cycles on the mechanical characteristics of polyurethane concrete, which revealed that the time node of freeze-thaw damage impacted the freeze-thaw resistance of polyurethane concrete susceptible to early freeze-thaw damage.

The early-age freeze-thaw damage polyurethane concrete was experimentally studied by controlling the time node of the freeze-thaw cycle and the curing environment. The test considered the time node, frequency of freeze-thaw damage of polyurethane concrete and the influence of subsequent curing environment and observed the mass change, relative dynamic elastic modulus, relative durability index, compressive strength and apparent damage of polyurethane concrete. The early mechanical properties of polyurethane concrete were studied by analyzing the change of numerical value. The microscopic mechanism of strength formation of polyurethane concrete was analyzed by XRD, FTIR and SEM image.

The closer the time of freeze-thaw damage was to the specimen hardening, the worse the mechanical properties and structure were, according to SEM photographs. For specimens with serial number of 12-groups, its compressive strength is only 82.39% of that of the standard group, even if the curing process continues after 20 times thawing, which increased early environment exacerbate strength loss in polyurethane concrete and also reduced freeze-thaw resistance. The findings of the tests reveal that curing can restore the freeze-thaw resistance of damaged polyurethane concrete. Curing in water has a better recovery impact than curing in air; the mechanical properties can be restored by sufficient re-curing time and good re-curing conditions.

By studying the freeze-thaw cycle test and test results of polyurethane concrete in different curing time nodes, the relationship between the mechanical properties of polyurethane concrete and the time node, number of freeze-thaw cycles, and subsequent maintenance environment was explored. Considering the special mechanism of strength formation of polyurethane concrete, the polyurethane concrete damaged by freeze-thaw has the ability to continue to form strength under subsequent maintenance. This experimental study can provide an analytical basis for the strength formation and reconditioning of polyurethane concrete structures subjected to freeze-thaw environments during the curing time under extreme natural conditions in fall and winter in actual projects.

This paper aims to devise a robust controller for the non-linear aircraft model using output feedback control topology in the presence of uncertain aerodynamic parameters.

Feedback linearization-based state feedback (SFB) controller is considered along with a robust outer loop control which is designed using Lyapunov’s second method. A high-gain observer (HGO) in accordance with the separation principle is used to implement the output feedback (OFB) control scheme. The robustness of the controller and observer is assessed by introducing uncertain aerodynamics coefficients in the dynamic model. The proposed scheme is validated using MATLAB/SIMULINK.

The efficacy of the proposed scheme is authenticated with the simulation results which show that HGO-based OFB control achieves the SFB control performance for a small value of the high-gain parameter in the presence of uncertain aerodynamic parameters.

A HGO for the non-linear model of aircraft with uncertain parameters is a novel contribution which could be further used for the unmanned aerial vehicles autopilot, flight trajectory tracking and path following.